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  1. Most students enter college without any exposure to polymer science, which leads to the poor understanding and slow implementation of plastics recycling programs in the United States. To address the knowledge gap in chemical recycling, we introduce a 2-part laboratory experiment that was conducted in multiple high schools and public outreach events to demonstrate the depolymerization of PET via aminolysis and the remanufacturing of cleaved PET fragments into a new aramid polymer. Student experiences were evaluated with two post-lab assignments. 
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    Free, publicly-accessible full text available December 11, 2024
  2. Abstract

    The World Magnetic Model (WMM) is a geomagnetic main field model that is widely used for navigation by governments, industry and the general public. In recent years, the model has been derived using high accuracy magnetometer data from the Swarm mission. This study explores the possibility of developing future WMMs in the post-Swarm era using data from the Iridium satellite constellation. Iridium magnetometers are primarily used for attitude control, so they are not designed to produce the same level of accuracy as magnetic data from scientific missions. Iridium magnetometer errors range from 30 nT quantization to hundreds of nT errors due to spacecraft contamination and calibration uncertainty, whereas Swarm measurements are accurate to about 1 nT. The calibration uncertainty in the Iridium measurements is identified as a major error source, and a method is developed to calibrate the spacecraft measurements using data from a subset of the INTERMAGNET observatory network producing quasi-definitive data on a regular basis. After calibration, the Iridium data produced main field models with approximately 20 nT average error and 40 nT maximum error as compared to the CHAOS-7.2 model. For many scientific and precision navigation applications, highly accurate Swarm-like measurements are still necessary, however, the Iridium-based models were shown to meet the WMM error tolerances, indicating that Iridium is a viable data source for future WMMs.

    Graphical Abstract

     
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  3. Abstract

    Characterization of Earth's magnetic field is key to understanding dynamics of the core. We assess whether Iridium Communications magnetometer data can be used for this purpose since. The 66 Iridium satellites are in 86° inclination, 780 km altitude, circular orbits, with 11 satellites in each of six orbit planes. In one day the constellation returns 300,000 measurements spanning the globe with <2° spacing. We used data from January 2010 through November 2015, and compared against International Geomagnetic Reference Field (IGRF‐11) to inter‐calibrate all data to the same model. Geomagnetically quiet 24‐h intervals were selected using the total Birkeland current, auroral electrojet, and ring current indices. Thez‐scores for these quantities were combined and the quietest 16 intervals from each quarter selected for analysis. Residuals between the data and IGRF‐11 yield consistent patterns that evolve gradually from 2010 to 2015. Residuals for each day were binned in 9° latitude by 9° longitude and the distributions about the mean in each bin are Gaussian with 1‐sigma standard errors of ∼3 nT. Spherical harmonic coefficients for each quiet day were computed and time series of the coefficients used to identify artifacts at the orbit precession (8 months) and seasonal (12 months) periods and their harmonics which were then removed by notch filtering. This analysis yields time series at 800 virtual geomagnetic observatories each providing a global field map using a single day of data. The results and CHAOS 7.4 generally agree, but systematic differences larger than the statistical uncertainties are present that warrant further exploration.

     
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